| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 郭幸甄 | zh_TW |
| DC.creator | Hsing-Chen Kuo | en_US |
| dc.date.accessioned | 2006-1-27T07:39:07Z | |
| dc.date.available | 2006-1-27T07:39:07Z | |
| dc.date.issued | 2006 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:444/thesis/view_etd.asp?URN=92223012 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 利用Suzuki coupling以及condenstation reaction我們成功的合成出接上電子予體（Donor）與電子受體（Acceptor）的七環十四碳烷（HCTD）化合物14、16、19、22、24、25以及26，並利用Wolff-Kishner reduction得到對照組（reference）化合物31、32、33、34、35以及36。
在這一系列化合物中，從螢光光譜我們可以很清楚看到在500 nm左右有CT band的產生，證明我們的系統具有光誘導電子轉移的機制，接著我們再配合熱力學ΔG的計算，以及動力學螢光的量測，
來討論我們所合成出的化合物。 | zh_TW |
| dc.description.abstract | Starting from Heptcyclo [6.6.0.02.6.03.13.04.11.05.9.010.14] tetradecane (HCTD), we were able to synthesize a series of donor-bridge-acceptor substituted derivatives by condensation reaction. The component for the condensation was 1,3-indanedione for the acceptor part. We also synthesized the reference compounds by using the Wolff-Kishner reduction. Fluorescence spectra provided evidence for efficient photoinduce electron transfer. | en_US |
| DC.subject | 電子轉移 | zh_TW |
| DC.subject | electron transfer | en_US |
| DC.title | 具備電子予體與受體之雙極性有機分子的合成與特性 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Synthesis and Properties of Dipolar Organic Molecules containing electron Donor and Acceptor Substituents | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |