| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 林慶龍 | zh_TW |
| DC.creator | Ching-Lung Lin | en_US |
| dc.date.accessioned | 2005-6-21T07:39:07Z | |
| dc.date.available | 2005-6-21T07:39:07Z | |
| dc.date.issued | 2005 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:444/thesis/view_etd.asp?URN=92223020 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 摘要
本文利用金屬鈀的催化反應，將螺環茀-吖啶及螺環雙茀的延伸物，做有效的結合，進而合成出一系列的高分子。螺環茀-吖啶具有剛性結構，所以擁有較高的熱穩定性及較高的玻璃轉換溫度，並且它也兼具電洞傳導物質的特性。這些高分子化合物，具有非常好的溶解度，可以溶於一般的有機溶劑，像是1, 2-二氯苯、二氯甲烷、四氫呋喃、甲苯及1, 2-二甲苯等。由示差熱分析儀及熱重分析儀中發現，高分子具有傑出的熱穩定性，且其玻璃轉換溫度幾乎都高於攝氏300度。所製作出來的元件，其最佳的效能如下，藍光部份的有機發光二極體其元件格式為(Glass/ITO(120nm)/PEDOT ： PSS(65nm)/ 高分子化合物ACOXP6(60nm)/Ca(30nm)/Al(130nm))，其最高效率為0.557(%)，而其最大亮度為 977 (cd/m2)，在CIE圖上的位置(0.17,0.09)， 而紅光部份的有機發光二極體其元件格式為(Glass/ITO(120nm)/PEDOT：PSS(80nm)/
高分子化合物ACTBP5(120nm)/LiF(0.7nm)/Al(130nm))，其最高效率為1.497(%) ， 而其最大亮度為4667(cd/m2) ， 在CIE 圖上的位置(0.65,0.34) ， 綠光部份的有機發光二極體其元件格式為(Glass/ITO(120nm)/PEDOT：PSS(50nm)/高分子化合物ACTBP6(120nm)/Ca(30nm)/Al(130nm))，其最高效率為0.849(%)，而其最大亮度為13874(cd/m2)，在CIE圖上的位置(0.37,0.58)，黃光部份的有機發光二極體其元件格式為(Glass/ITO(120nm)/PEDOT：PSS(65nm)/ 高分子化合
物IrP2(60nm)/LiF(0.7nm)/Al(130nm))，其最高效率為1.153(%)，而其最大亮度為671(cd/m2)，在CIE圖上的位置(0.47，0.52). | zh_TW |
| dc.description.abstract | Abstract:
A series of novel light-emitting copolymers derived from spiro-fluorene-acridine and spiro-bifluorene, are prepared by palladium-catalyzed Suzuki coupling reaction.Spiro-fluoreneacridine
have rigid structure so copolymers show high Tg and it can also be utilized as hole-transporting material.These polymers have good solubility in common organic solvents, such as 1,2-dichlorobenzene, CH2Cl2, THF, toluene, and o-xylene.DSC and TGA studies reveal that novel polymers possess excellent thermal stability with high glass transition temperatures (Tg >300oC).Blue light-emitting device (Glass/ITO(120nm)/PEDOT：PSS(65nm)/ACOXP6(60nm)/Ca(30nm)/Al(130nm)) ， showed maximal externalquantum efficiency of 0.557% and the highest brightness of 977 cd/m2,and CIE(0.17,0.09). Red light-emitting device (Glass/ITO(120nm)/PEDOT：PSS(80nm)/ACTBP5(120nm)/LiF(0.7nm)/Al(130nm))，showed maximal external quantum efficiency of 1.497% and the highest brightness of 4667 cd/m2, and CIE(0.65,0.34). Green light-emitting device (Glass/ITO(120nm)/PEDOT：PSS(50nm)/ACTBP6(120nm)/Ca(30nm)/Al(130nm)) showed maximal external quantum efficiency of 0.849% and the highest brightness of 13874cd/m2, and CIE(0.37,0.58).Yellow light-emitting device
(Glass/ITO(120nm)/PEDOT：PSS(65nm)/IrP2(60nm)/LiF(0.7nm)/Al(130nm)) showed maximal external quantum efficiency of 1.153% and the highest brightness of 671cd/m2, and CIE(0.47，0.52). | en_US |
| DC.subject | 螺環茀-吖啶 | zh_TW |
| DC.subject | 螺環雙茀的延伸物 | zh_TW |
| DC.subject | spiro-fluorene-acridine | en_US |
| DC.subject | spiro-bifluorene | en_US |
| DC.title | 螺環茀-吖啶高分子在發光二極體上的應用 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Spiro-fluorene-acridine Polymers for Light Emitting Diodes | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |