Zr48Cu36Al8Ag8Six(x = 0.00~1.00)鋯基金屬玻璃在硫酸與氯鹽環境中之腐蝕行為

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洪婉毓(Wan-yu Hung) 查詢紙本館藏

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論文名稱

Zr48Cu36Al8Ag8Six(x = 0.00~1.00)鋯基金屬玻璃在硫酸與氯鹽環境中之腐蝕行為
(Corrosion behavior of Zr48Cu36Al8Ag8Six(x = 0.00~1.00) bulk metallic glasses (BMGs) in sulfuric acid and sodium chloride solutions)

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摘要(中)

本論文在探討Zr48Cu36Al8Ag8Six鋯基金屬玻璃中矽(Si)含量在0.00, 0.25, 0.50, 0.75, 1.00 at.%等範圍內對其腐蝕行為之影響，腐蝕溶液分為氯化鈉(NaCl)和硫酸(H2SO4)兩種環境，研究方法包含浸泡量測、直流電化學極化法(線性極化、Tafel極化、動態極化)與交流電化學阻抗頻譜法等來研究其腐蝕行為。
腐蝕測試前後採用熱示差分析儀(DSC)熱性質量測材料，藉以判別玻璃形成能力(GFA)與材料腐蝕行為之關係，此外用掃描式電子顯微鏡(SEM)、原子力顯微鏡(AFM)進行表面形貌觀察，電子微探儀(EPMA)以分析腐蝕後元素分佈及X光光電子能譜儀(XPS)進行腐蝕生成物的探討。
綜合浸泡量測與電化學量測實驗結果顯示：含0.25 at.%矽之鋯基金屬玻璃抗蝕性最高，且在硫酸(H2SO4)環境中顯示出活性-鈍化轉變區，表面鈍化膜藉由XPS分析得知：含0.25 at.%矽之鋯基金屬玻璃，其表面由ZrO2與SiO2組成之峰值面積最大，此兩種保護性氧化物的貢獻，使其擁有最佳抗蝕性。

摘要(英)

Corrosion behavior of Zr48Cu36Al8Ag8Six (x=0.00, 0.25, 0.50, 0.75, 1.00 at.%) bulk metallic glasses (BMGs) in sodium chloride and sulfuric acid solutions were investigated by immersion test, direct current (dc) polarization techniques (Tafel polarization, linear polarization resistance, potentiodynamic polarization) and electrochemical impedance spectroscopy.
Instrumental analyses such as DSC, SEM, AFM were carried out prior to and post the corrosion test to find the correlation between the corrosion behaviour and structure of the BMG； EPMA and XPS analyses provided the relationship between the corrosion and composition of the specimens.
According to the results from immersion test and electrochemical studies, we concluded that the specimens of BMG containing 0.25 at.%-Si revealed the best corrosion resistance. There was an occurrence of active - passive transition on the potentiodynamic polarization curve for the specimens immersed in sulfuric acid. The presence of passive film on the specimens was confirmed in terms of XPS analyses. Dominant contribution of the passive film indicated by the strongest peaks of ZrO2 and SiO2 led to the best corrosion resistance of the specimens with 0.25 at.%Si.

關鍵字(中)

★ 金屬玻璃
★ 矽
★ 腐蝕
★ 氯化鈉
★ 硫酸

關鍵字(英)

★ Metallic glasses
★ Zr-Cu-Al-Ag-Si
★ corrosion
★ NaCl
★ H2SO4

論文目次

摘要 I
Abstract II
目錄 IV
表目錄 VII
圖目錄 XI
第一章緒論 1
1-1 前言 1
1-2 研究動機 2
1-3 研究目的與實驗架構 3
第二章理論背景與文獻回顧 4
2-1 非晶質合金 4
2-1-1 非晶質合金特性 4
2-1-2 機械性質 4
2-1-3 耐蝕性 5
2-1-4 玻璃轉換溫度(Tg) 5
2-2 非晶質合金形成法則 5
2-3 玻璃形成能力(Glass Forming Ability, GFA)準則 6
2-3-1 簡化玻璃溫度(Trg) 6
2-3-2 過冷液態溫度區(ΔTx) 7
2-3-3 γ參數 7
2-3-4 γm參數 8
2-4 塊狀金屬玻璃相關腐蝕研究 8
2-5 電化學測試法之原理與相關理論 10
2-5-1 開路電位(Open Circuit Potential) 10
2-5-2 線性極化(Linear polarization) 10
2-5-3 動態極化(Potentiodynamic polarization)之Tafel掃描 10
2-5-4 交流阻抗頻譜法(Electrochemical Impedance Spectroscopy) 11
2-5-5 等效電路圖及模擬 14
第三章實驗方法及步驟 15
3-1 試片準備與規格 15
3-2 實驗方法 16
3-2-1 溶液配製 16
3-2-2 浸泡實驗 16
3-2-3 電化學實驗 16
3-2-3-1 開路電位 17
3-2-3-2 線性極化測試 17
3-2-3-3 Tafel極化測試 17
3-2-3-4 交流阻抗頻譜測試 17
3-3 表面分析儀器 18
3-3-1 X光光電子能譜儀/歐傑電子能譜儀(Electron Spectroscopy for Chemical Analysis, ESCA/Auger) 18
3-3-2 原子力顯微鏡 (Atomic Force Microscopy, AFM) 18
3-3-3 場發射掃描式電子顯微鏡 (Field Emission Scanning Electron Microscope, FE-SEM) 18
3-3-4 電子微探儀(Electron Probe X-Ray Microanalyzer, EMPA) 19
3-4 金屬玻璃特性分析 19
3-4-1 X光繞射儀分析儀(X-ray Diffractometer, XRD) 19
3-4-2 熱示差分析儀(DSC) 19
第四章結果 20
4-1 X光繞射分析 20
4-2 腐蝕性離子影響測試 20
4-2-1 浸泡量測法 20
4-2-2 線性極化法 20
4-2-3 Tafel極化法 21
4-2-4 動態極化法 22
4-2-5 交流阻抗頻譜分析(EIS) 與等效電路模擬 23
4-3 表面分析 24
4-3-1 SEM表面分析 24
4-3-2 AFM表面分析 26
4-3-3 XPS表面分析 26
4-3-4 EPMA表面分析 27
4-4-1 非恆溫熱性質分析 27
第五章討論 30
5- 1 含矽量對於抗蝕性能力探討 30
5- 2 腐蝕環境因子 32
5-2-1 氯離子(Cl-)影響 32
5-2-2 硫酸根離子(SO42-)影響 32
5-3 表面分析 33
5-3-1 表面形貌分析討論 33
5-3-2 XPS分析之腐蝕機制討論 34
第六章結論與展望 36
參考文獻 37

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指導教授

林景崎(Jing-chie Lin)

審核日期

2013-6-27

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