甲烷固態氧化物燃料電池複合系統分析

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黃子垣(Tzu-yuan Huang) 查詢紙本館藏

畢業系所

能源工程研究所

論文名稱

甲烷固態氧化物燃料電池複合系統分析
(Analysis of Methane Fed Solid Oxide Fuel Cell Hybrid Systems)

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摘要(中)

本研究針對中溫質子傳導型固態氧化物燃料電池複合系統分析。根據理論利用Matlab計算出燃料電池之性能曲線，並應用於商用軟體Thermolib進行系統模擬。文中建立四種不同燃料電池複合系統，各系統之系統配置有些許不同，並且在相同操作條件下進行比較，操作條件為燃料當量比1.4 ~ 1.7、空氣當量比2 ~ 4。

摘要(英)

In this research, the performance of intermediate-temperature proton-conducting solid oxide fuel cell hybrid systems is investigated. It is analyzed by using Matlab/Simulink/Thermolib. There are four different fuel cell hybrid systems. The configuration of each system is slightly different, but is analyzed under the same operating conditions. Flow rates of hydrogen and air are controlled by assigning different stoichiometric ratio, which are 1.4 - 1.7 and 2 - 4 respectively.

關鍵字(中)

★ 中溫
★ 質子傳導
★ 固態氧化物燃料電池
★ 渦輪機
★ 甲醇合成反應
★ 碳捕捉及再利用

關鍵字(英)

★ Intermediate-temperature
★ Proton-conducting
★ Solid oxide fuel cell
★ Micro gas turbine
★ Methanol synthesis reaction
★ Carbon capture and reuse

論文目次

目錄
中文摘要 I
ABSTRACT III
致謝 V
目錄 VII
圖目錄 XI
表目錄 XIV
符號表 XVII
第一章緒論 1
1.1 前言 1
1.2 固態氧化物燃料電池複合系統 2
1.2.1固態氧化物燃料電池之工作原理 2
1.2.2 燃料電池極化現象 5
1.2.3固態氧化物燃料電池結構 7
1.2.4 固態氧化物燃料電池系統 8
1.2.5 熱回收系統 10
1.2.6 減碳系統： 10
1.3 文獻回顧 10
1.3.1 SOFC數學模型： 10
1.3.2 SOFC系統： 14
1.3.3 碳捕捉與應用 16
1.4 研究動機與方向 17
第二章理論分析 19
2.1 問題描述與假設 19
2.2 系統模型 19
2.2.1 固態氧化物燃料電池模型 19
2.2.4 壓縮機 24
2.2.5 混和器 25
2.2.6 重組/合成反應器 25
2.2.7 熱交換器 26
2.2.8 微氣渦輪機(Micro gas turbine, MGT) 27
2.2.9 後燃器 27
2.2.10 氫氣傳輸膜(Hydrogen transport membrane, HTM) 28
2.2.11 水分離器 28
2.2.12 電源轉換器 DC/AC 28
2.2.13 效率定義 28
2.3 參數條件 30
第三章數值方法與驗證 32
3.1 數值方法 32
3.2 程式驗證 35
第四章結果與討論 39
4.1 質子傳導型固態氧化物燃料電池性能曲線 39
4.2 系統設計之比較 42
4.2.1 燃料及空氣當量對系統A的影響 49
4.2.2 燃料及空氣當量對系統B的影響 55
4.2.3 燃料及空氣當量對系統C的影響 63
4.2.4 燃料及空氣當量對系統D的影響 74
4.3系統減碳效益 86
第五章結論與未來建議 87
5.1 結論 87
5.2 未來建議 88
第六章參考文獻 89
附錄 A 系統各節點之氣體組成表 93

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指導教授

曾重仁(Chung-jen Tseng)

審核日期

2015-7-9

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