中壢紅土對水中染料之吸附與催化

以作者查詢圖書館館藏

、以作者查詢臺灣博碩士

、以作者查詢全國書目

、勘誤回報

、線上人數：35

、訪客IP：18.216.208.243

姓名

謝豐遠(Xie Fengyuan) 查詢紙本館藏

畢業系所

環境工程研究所

論文名稱

中壢紅土對水中染料之吸附與催化
(Fenton-like reaction and adsorption of dyes by using Chungli laterite)

相關論文

★ 工業廢水對灌溉水質影響之研究-以黃墘溪為例	★ 廢冷陰極管汞回收處理效率之研究
★ 室內懸浮微粒與生物氣膠之相關性探討-以某醫學中心為例	★ 化學機械研磨廢液對工業區污水處理效益與操作成本之影響
★ 網路數位電力監測系統於大學用電行為分析之研究	★ 光電業進行自願性碳標準(VCS)減量計畫可行性之研究
★ 污染農地整治後未能符合農用成因之探討	★ 桃園縣居家入侵紅火蟻防治方法探討
★ 印刷電路板產業濕式製程廢液回收鈀金屬可行性之研究	★ 不同表面特性黏土催化高分子凝聚劑與消毒劑(氯)反應之研究
★ 界面活性劑對土壤/水系統中有機污染物分佈行為之研究	★ 淨水程序中添加高分子凝聚劑對混凝與加氯處理效應之研究
★ 土壤無機相對揮發性有機污染物吸∕脫附行為之影響	★ 土壤對Triton 系列各EO鏈選擇性吸附之研究
★ 土壤有機質對土壤/水系統中低濃度非離子有機污染物吸附行為之研究	★ 不同表面特性黏土催化水中有機物之氯化反應研究

檔案

[Endnote RIS 格式]

[Bibtex 格式]

[相關文章]

[文章引用]

[完整記錄]

[館藏目錄]

[檢視]

[下載]

本電子論文使用權限為同意立即開放。
已達開放權限電子全文僅授權使用者為學術研究之目的，進行個人非營利性質之檢索、閱讀、列印。
請遵守中華民國著作權法之相關規定，切勿任意重製、散佈、改作、轉貼、播送，以免觸法。

摘要(中)

紡織工業在台灣已發展超過50年，經過多年的努力為台灣創造了相當高的經濟價值，而染整產業在紡織工業中更佔據了相當重要的角色，經過染整加工能大幅提升的產品的附加價值並提升紡織工業在國際市場的競爭力，但在染整產業成長的同時也產生了大量染料廢水的問題。目前廢水處理大多使用化學以及生物的方法，此二法可以處理大部分的污水使之達到放流的標準，但對於染整廢水其高色度的特性就顯得相當棘手，因此在處理染料廢水問題上通常需仰賴高級處理方法的使用才能解決。
傳統之高級處理方法中以吸附的效果表現較好，但使用活性碳吸附之成本較高，而且染整加工過程產生的廢水具有排放量大、含有纖維雜質、酸鹼類、大量的殘餘染料等特性，大多數方法很難完善處理染料廢水。本研究以中壢紅土進行fenton-like氧化法處理染料廢水，而中壢紅土具有容易獲得、成本低之優點，因此可以解決許多高級處理法成本過高的問題。本研究結果顯示不同的過氧化氫及紅土添加量會影響染料的去除效果。紅土顆粒大小影響反應的進行，在吸附與fenton-like氧化效果均以顆粒小者為佳。紅土的吸附效果與fenton-like氧化會互相影響，當吸附效果好時fenton-like氧化效果會降低。在以攝氏400度及700度鍛燒紅土進行fenton-like反應，以400度鍛燒土處理能力較好。三種染料的去除效果比較，以結晶紫最佳。最後本研究將紅土壓碇成粒狀，經過鍛燒後製成可以重複使用的紅土粒，實驗結果在重複使用四次時仍能達到75%以上的去除率。

摘要(英)

The textile industry in Taiwan has been developed over 50 years, and it created high economic value for many years. Textiles plays an important role in apparel industry, because of the ability for moving towards high value-added products. Unfortunately, human appealing and wear glamorous clothes have ended up causing harm to the environment. The textile industry is one of the most pollutants releasing industries of the world. Most of primary and secondary treatment processes can deal with wastewaters. However, textile dyeing wastewater which containing versatile components, including many aerosols, high chroma, high BOD and COD, it lead difficult to remove textile dyeing wastewater only by use primary and secondary treatment. Therefore, it’s important to create a novel way to treat textile dyeing wastewater.
In this study we use Fenton-like reaction to create hydroxyl radicals which are among the strongest oxidizing agents and are able to decolourise a wide range of dyes. For Fenton-like reactions we selected Chungli laterite as the iron source, which has been recognized that Fe(OH)2+ can lead to the formation of hydroxyl radical (HO∙) and Fe(Ⅱ) through a ligand-to-metal charge transfer pathway. Our investigation reveals that dye in water not only decolourisation by Fenton-like reaction but also adsorption by laterite. Meanwhile, it was observed that dyes adsorped by laterite result in low Fenton-like reaction efficiency. Additional experiments were carried out using calcination laterite by 400 degrees Celsius and 700 degrees Celsius, where Fenton-like reactions were characterized with different pH, H2O2 dosage and reaction time. Results demonstrated that the 400 degrees Celsius calcination laterite was the most effective matrix for Fenton-like reaction. It’s also show that the most effective to dyes decolourise was crystal violet. We also pressed laterite as a cake for the re-use of Fenton-like reaction, and the effective to decolourise crystal violet is still more than 75% after four times reused. Our study may offer the possibility of the great potential applications of the calcination laterite in wastewater treatment areas especially for those containing compounds which are not easy to remove by traditional treatment processes.

關鍵字(中)

★ 染料
★ 吸附
★ 紅土
★ 過氧化氫
★ 鍛燒

關鍵字(英)

★ Fenton-like
★ Fenton
★ adsorption
★ laterite
★ dye
★ calcination

論文目次

目錄 I
圖目錄 IV
表目錄 VII

第一章前言 1

1-1 研究緣起 1
1-2 研究內容與目的 2

第二章文獻回顧 4

2-1 染整產業廢水概況 4
2-2 染整廢水處理方式 5
2-3 Fenton法原理 6
2-4 Fenton-like法原理 8
2-4-1 Fenton-lik法之氧化原理與機制 8
2-4-2 環境因子對Fenton-like氧化效率的影響 10
2-5 吸附機制與吸附模式 15
2-5-1 吸附類型 16
2-5-2 等溫吸附模式 17
2-5-3 等溫吸附曲線 21
2-5-4 反應動力學 23
2-6 土壤基本性質 25

第三章研究方法 31

3-1 研究內容與流程 31
3-2 實驗設備 34
3-3 實驗材料 39
3-4 實驗方法 42
3-4-1 土壤之前處理 42
3-4-2 土壤吸附染料實 42
3-4-3 fenton-like法降解染料實驗 44
3-4-4 土壤造粒 44
3-4-5 土壤鍛燒 45

第四章結果與討論 46

4-1 中壢紅土基本特性分析 46
4-1-1 中壢紅土之XRD圖譜 46
4-1-2 ASAP氮氣吸脫附曲線 48
4-2 中壢紅土對染料吸附之影響 53
4-2-1 染料之全波長掃描 53
4-2-2 染料之檢量線 55
4-2-3 染料自然降解實驗 56
4-2-4 中壢紅土對染料之吸附平衡時間 58
4-2-5 中壢紅土對染料之等溫吸附曲線 59
4-3 中壢紅土對染料之吸附與催化 65
4-3-1 過氧化氫添加對催化染料之影響 65
4-3-2 不同土壤對催化反應之影響 68
4-3-3 不同染料對fenton-like反應之影響 74
4-4 中壢造粒紅土對染料之吸附與催化 75
4-4-1 造粒紅土與非造粒紅土催化反應之差別 76
4-4-2 過氧化氫添加量對造粒紅土催化反應之影響 78
4-4-3 不同鍛燒溫度對催化反應之影響 80
4-4-4 中壢造粒紅土對不同染料之催化反應 82
4-5 中壢造粒紅土對染料催化之重複利用性 83

第五章結論與建議 86

5-1 結論 86
5-2 建議 88

參考文獻 89

參考文獻

參考文獻
1. 李光中、劉新校、侯佳蕙，淺談染整廢水之處理，環保簡訊，第二十一期，2013
2. 廖世芳，染整工業21世紀水處理技術需求，水再生及再利用研討會，2002
3. 行政院環境保護署環署水字第1040110356號令修正發布第二條條文，放流水標準，2016
4. 水中真色色度檢測方法-分光光度計法，環署檢字第0990084622號公告，2010
5. 周明顯，放流水處理技術檢討-廢水處理技術對真色色度符合環保法令之有效性研究，科技計畫，2002
6. Fenton, H. J. H. “Oxidation of tartaric acid in presence of iron. Journal of Chemical Society”, Vol. 65, pp. 889-910,1894
7. Daniel L. Pardieck, Edward J. Bouwer, Alan T. Stone “Hydrogen peroxide use to increase oxidant capacity for in situ bioremediation of contaminated soils and aquifers” Journal of contaminant Hydrology, Vol.9, pp.221-242, 1992.
8. Marianne E. Balmer, Barbara Sulzberger “Atrazine Degradation in Lrradiated Iron/Oxalate Systems: Effects of pH and Oxalate” Environ. Sci. Technol., Vol.33, pp. 2418–2424, 1999.
9. C.P.Huang, Chengdi Dong, Zhonghung Tang “Advanced chemical oxidation: Its present role and potential future in hazardous waste treatment” Waste Management, Vol. 13, pp. 361-377, 1993.
10. Rajagopalan Venkatadri and Robert W. Peters. “Chemical Oxidation Technologies: Ultraviolet Light/Hydrogen Peroxide, Fenton′s Reagent, and Titanium Dioxide-Assisted Photocatalysis” Hazardous Waste and Hazardous Materials, Vol.10, 2009.
11. Ewa Lipczynska Kochany, Gregor Sprah Susan Harms, “Influence of some groundwater and surface waters constituents on the degradation of 4-chlorophenol by the Fenton reaction” Chemosphere, Vol.30, PP. 9-20, 1995.
12. C. L. Hsueha, Y. H. Huanga, C. C. Wangb, C. Y. Chena, “Degradation of azo dyes using low iron concentration of Fenton and Fenton-like system” Chemosphere, Vol.58, pp.1409-1414,2005
13. Richard J. Watts, Matthew D. Udell, Paul A. Rauch, Solomon W. Leung. “Treatment of Pentachlorophenol-Contaminated Soils Using Fenton′s Reagent” Hazardous Waste and Hazardous Materials, Vol.7, 2009.
14. Bryan W. Tyre, Richard J. Watts , Glenn C. Miller, “Treatment of Four Biorefractory Contaminants in Soils Using Catalyzed Hydrogen Peroxide” Environmental Quality Abstract, Vol. 20, pp. 832-838.
15. Md. Abu Jafar Khan, Richard J. Watts “Mineral-catalyzed peroxidation of tetrachloroethylene” Water, Air and Soil Pollution, Vol. 88, pp 247–260.
16. Richard J. Watts, Daniel R. Haller, Alexander P. Jones, Amy L. Teel, “A foundation for the risk-based treatment of gasoline-contaminated soils using modified Fenton′s reactions” Journal of Hazardous Materials, Vol.76, Pages 73-89,2000.
17. Alexandra Masarwa, Sandra Rachmilovich-Calis, Naomi Meyerstein, Dan Meyerstein, “Oxidation of organic substrates in aerated aqueous solutions by the Fenton reagent” Coordination Chemistry Reviews, Vol. 249, pp. 1937-1943,2005.
18. Alireza Khataee, Fatemeh Salahpour, Mehrangiz Fathinia, Behnam Seyyedi, Behrouz Vahid, “Iron rich laterite soil with mesoporous structure for heterogeneous Fenton-like degradation of an azo dye under visible light” Journal of Industrial and Engineering Chemistry, pp.129-135,2015.
19. C.W. Yang, D. Wang, Q. Tang, “The synthesis of NdFeB magnetic activated carbon and its application in degradation of azo dye methyl orange by Fenton-like process”, J. Taiwan Inst. Chem., pp.2584–2589, 2014
20. H.Y. Xu, W.C. Liu, S.Y. Qi, Y. Li, Y. Zhao, J.W. Li, “Kinetics and optimization of the decoloration of dyeing wastewater by a schorl-catalyzed Fenton-like reaction”, J. Serb. Chem., pp.361–377, 2014.
21. Y.H. Huang, C.C. Su, Y.P. Yang, M.C. Lu, “Degradation of aniline catalyzed by heterogeneous Fenton-like reaction using iron oxide/SiO2”, Environ. Prog. Sustain., pp.187–192, 2013.
22. Y. Feng, D.L. Wu, D. Duan, L.M. Ma, “Fenton-like oxidation of refractory chemical wastewater using pyrite”, Adv. Mater., pp.2518– 2525, 2012.
23. Nannan Wanga, Tong Zheng, Guangshan Zhang, Peng Wang, “A review on Fenton-like processes for organic wastewater treatment”, Journal of Environmental Chemical Engineering, Volume 4, March, pp. 762–787, 2016.
24. Carlton L. Ho, Maher A.-A. Shebl, and Richard J. Watts., “Development of an injection system for in situ catalyzed peroxide remediation of contaminated soil. Hazardous”, Waste and Hazardous Materials, Vol. 12, pp.15-25.
25. H. Zhang, X.G. Wu, X.W. Li, “Oxidation and coagulation removal of COD from landfill leachate by Fered-Fenton process”, Chem. Eng. J., pp.188–194, 2012.
26. Watts, R. J., Foget, M. K., Kong, S. H., Amy, L. T. “Hydrogenperoxide decomposition in model subsurface systems”, Journal of Hazardous Materials, Vol. 69, pp. 229-243.,1999
27. Munoz, G. Pliego, Z.M.D. Pedro, J.A. Casas, J.J. Rodriguez, “Application of intensified Fenton oxidation to the treatment of sawmill Wastewater”, Chemosphere, pp.34–41, 2014
28. Kong, S. O., Watts, R. J., Choi, J. H., “Treatment of petroleumcontaminated soils using iron mineral catalyzed hydrogen peroxide”, Chemosphere, Vol. 37, pp. 1473-1482, 1998
29. Watts, R. J., Udell, M. D., Rauch, P. A., Leung, S. W., “Treatment of pentachlorophenol contaminated soils using Fenton’s reagent” Hazardous Waste and Hazardous Materials, Vol. 7, pp. 335-345, 1990
30. Yeh, K. J., Kao, Y. A., Cheng, C. P., “Oxidation of chlorophenols in soil at natural pH by catalyzed hydrogen peroxide: the effect of soil organic matter”, Chemosphere, Vol. 46, pp. 67-73,2002
31. Wai P. Kwan, Bettina M. Voelker, “Rates of Hydroxyl Radical Generation and Organic Compound Oxidation in Mineral-Catalyzed Fenton-like Systems”, Environ. Sci. Technol.,37 , pp.1150–1158, 2003.
32. Brunauer, S., L. S. Deming, W. S. Deming, E. Teller, J. Am.Chem.Soc., 62, pp.1723, 1940
33. R. S. Juang, F. C. Wu, and R. L. Tseng, “Mechanism of Adsorption 105 of Dyes and Phenols from Water Using Activated Carbons Prepared from Plum Kernels”, J Colloid Interface Sci, vol. 227, pp. 437-444, 2000
34. Y. S. Ho and G. McKay, “Comparative sorption kinetic studies of dye and aromatic compounds onto fly ash”, Journal of Environmental Science and Health, vol. 34, pp. 1179-1204, 1999
35. 中央大學環工所土壤污染防治上課講義
36. 萬獻銘、唐淑芬、呂仲泰，林口臺地紅土之黏土礦物組成、構造及性質，工業技術研究院能源與礦業研究所，1985
37. 萬獻銘、陳淑華、呂仲泰，林口臺地紅土基本特性研究，工業技術研究院能源與礦業研究所，1987
38. 翁作新、張惠煌、陳文泓，林口紅土微觀土粒結構之研究，行政院國家科學委員會專題研究計畫，1985
39. 國立台灣大學農業化學系，土壤調查與整治研究室http://lab.ac.ntu.edu.tw/soilsc/sc/sc_box_taiwan.html

指導教授

李俊福

審核日期

2017-10-19

推文