摘要(英) |
The color filter process uses a large amount of dyed photoresist and generate colored wastewater. Removal of color by sodium hypochlorite (NaOCl) is popular because of easy operation and low cost. However, the residual chlorine and by-product may affect the following treatment equipment, the effluent water quality, and the aquatic environment.
In this study, reuse of the ion exchange resin from the ultrapure water process of the photoelectric industry for the removal of residual chlorine and chloride in wastewater was evaluated. It was found that when the solution pH was 10 and the space velocity was 6, the removal of chloride is the most efficient. At the optimal operating conditions the solution pH, conductivity, and residual chlorine of the chlorinated wastewater was examined. The results showed that the conductivity and the residual chlorine were also effectively removed. This work shows that chlorination can effectively reduce the color in the photoresistant wastewater. The residual chlorine and chloride can be removed by ion exchange. Moreover, resin from ultrapure water process can be used in the removal of residual chlorine and chloride. Thus, the amount of wasted resin can be significantly reduced.
|
參考文獻 |
1.國家發展委員會,https://www.ndc.gov.tw。
2.Tunay, O., Kabdasli, J., Eremektar, G., and Orbon, D.,(1996)“Color removal from textile wastewater,”Water Science and Technology, 34(11), pp.9-16。
3.陳立言,殘餘氯對吳郭魚呼吸及代謝之影響,國立台灣大學漁業科學研究所碩士論文,1992。
4.中華映管教育學習網站,https://www.cptt.com.tw。
5.光電業資源化應用技術手冊-薄膜電晶體液晶顯示器,財團法人台灣綠色生產力基金會 ,2003。
6. Chu, W. and Ma, C. W.,(1998)“Reaction kinetics of UV-decolourization for dye materials,”Chemosphere, 37(5), pp. 961-974。
7. Porter, J. J.,(1972)“Treatment of textile waste with activate carbon,”American Dyestuff Reporter , 61, pp.8-12。
8. Thompson, H.S., “On the Absorbent Power of Soils.”, J.Royal Agr. Soc., 11, 68, 1850。
9. Gans, R., Jahrb. Preuss., “Geol”. Landesanstalt (Berlin), 26, 179, 1905.
10.Weber, W.J.Jr., “Physiconchemical Processes for Water Quality Control”,Wiley-Interscience,New York,1972。
11.曾迪華,「工業污染防治技術手冊-工業廢水離子交換處理」,經濟部工業局,財團法人中國技術服務社工業污染防治技術服務團,1993。
12.張亦成,離子交換樹脂廠內再利用可行性之研究,國立中央大學環境工程研究所碩士論文,2015。
13.楊岳軍,「離子交換樹脂在重金屬廢水處理之應用」,重金屬廢水處理技術研討會,工研院化工所,新竹,1989。
14.侯萬善,離子交換(原文:USEPA EPA 625/-81-007),台灣大學圖書館,1981。
15.李耀辰、鮑建國、周旋等,高鹽度有機廢水對生物處理系統的影響研究進展,環境科學與技術,2006。
16.陳信吉,高級廢水處理報告離子交換法,崑山科技大學環境工程系,2007。
17.甘佳欣,以次氯酸去除染整廢水色度之反應動力學研究,國立中山大學環境工程研究所碩士論文,2000。
18. Kim, Y. H., Robert Hensley.,(1997)“Effective control of chlorination and dechlorination at wastewater treatment plants using redox potential,” Wat. Environ. Res., 69(5), pp. 1008-1014。
19.黃騰龍,“工業水處理”,正文書局,1989。
20.環保署水質保護網,https://water.epa.gov.tw/page2_1.aspx。
21.李中光、邱惠敏,活性污泥法常見問題與對策,環保簡訊,2014, 第24期。
22.楊萬發,“水及廢水處理化學”,茂昌圖書有限公司,1994。
23. William, B., Lew, C. S., and Loh, J. Y.,(1998)“Predictions of potential human health and ecological risks from power plant discharges of total residual chlorine and chloroform into rivers,” Environmental Science & Technology, 32 (14), pp. 2162-2171。
24. Mattice, J. S., and Tsai, S. C.,(1984)“Total Residual Chorine as a Regulatory Tool,”In Water Chorination , 4, pp.901。
|