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姓名 徐明偉(Ming-Wei Hsu) 查詢紙本館藏 畢業系所 化學工程與材料工程學系 論文名稱 以刮刀塗佈法刮塗鈣鈦礦層及電洞傳輸層 用於製備高效率鈣鈦礦太陽能電池
(Fabrication of Perovskite- and Hole-Transporting Layer by Blade Coating for High-Performance Perovskite Solar Cells)相關論文 檔案 [Endnote RIS 格式] [Bibtex 格式] [相關文章] [文章引用] [完整記錄] [館藏目錄] 至系統瀏覽論文 (2025-7-1以後開放) 摘要(中) 隨著鈣鈦礦太陽能電池蓬勃發展,眾多海內外學者陸續投入研究製程以及材料上的改善,以提高最終的光電轉換效率,在實驗室中最常使用的製程方法為刮刀塗佈法以及旋轉塗佈法,其中刮刀塗佈法有大面積製程、快速製程以及使用較少的前驅溶液等優點。
使用溶液製程處理電洞傳輸層的過程中,若電洞傳輸材料的溶解度不好,會導致製程時成膜性不佳,無法忠實呈現材料的特性。本實驗選用兩種電洞傳輸材料,分別是溶解度好的YKP03以及溶解度差的ZYW01,探討不同製程方式與材料溶解度對成膜之後表面形態的影響;由於旋轉塗佈法無法控制基板溫度,使其只能於室溫下操作,而刮刀塗佈法則可以控制基板溫度,可依照不同的條件選擇刮刀塗佈的溫度,以溶解度好的材料YKP03來說,摻雜(doping)條件於60°C,未摻雜(doping free)條件於125°C下進行刮刀塗佈法,能獲得最佳的光伏表現;以溶解度差的電洞傳輸材料ZYW01來說,由於旋轉塗佈法無法控制基板溫度,即使溶液加熱到溶解所需的溫度,在旋轉塗佈的過程中也會因溫度下降而析出,導致成膜性不佳,元件光電轉換效率為1.22%,此時使用刮刀塗佈法,則可有效的改善此一現象,控制基板溫度使得電洞傳輸材料溶液在塗佈的過程中維持其溶解所需要的溫度,進而改善電洞傳輸層之形態,在125°C下進行刮刀塗佈法所製備之元件光電轉換效率為10.84%。摘要(英) With the development of the perovskite solar cells (PSCs), many scholars have successively invested in research processes and material improvements to improve the photoelectric conversion efficiency(PCE). The most commonly used coating methods in the laboratory are blade coating and spin coating. The blade coating has advantages such as relatively fast and facile processing steps and much less precursor solution is wasted compared to spin coating
If the solubility of the hole-transporting material (HTM) is not good, it will cause the hole-transporting layer (HTL) has poor film forming properties during the solution coating process. It may lead HTMs display the property which is not reality. We choose two HTMs for the experiment. There are YKP03 and ZYW01, which solubility is good and poor. Study the influence of different coating methods and HTM solubility on the surface morphology. Spin coating method can only be operated at room temperature, because it cannot control the substrate temperature. However the blade coating method can control the temperature of substrate. According to different conditions, we can select the proper temperature for the experiment. For YKP03, a HTM with good solubility, blade coating at 60°C and 125°C for doping and doping free condition have the best film morphology. For ZYW01, a HTM with poor solubility, even if the solution is heated to the temperature required for dissolution, it will precipitate due to the temperature drop during the spin coating process. This results in poor film formation, and PCE of the device is 1.22%. At this time, blade coating method can improve this situation. The substrate is maintained at the temperature required for HTM dissolution. Improve the morphology of HTL. The PCE of device is 10.84%.關鍵字(中) ★ 鈣鈦礦太陽能電池
★ 刮刀塗佈法
★ 電洞傳輸材料關鍵字(英) ★ Perovskite Solar Cells
★ Blade coating
★ Hole-transporting materials論文目次 目錄
第一章 緒論 1
1-1前言 1
1-2 太陽能電池發展歷史與種類 2
1-2-1 無機太陽能電池 3
1-2-2 有機太陽能電池 3
1-2-2-1 小分子有機太陽能電池(Small-Molecule solar cells)…...4
1-2-2-2 高分子有機太陽能電池(Polymer solcar cells) ……...…..4
1-2-2-3染料敏化太陽能電池(Dye-sensitized solar cells) ………..5
1-3 文獻回顧 6
1-3-1 鈣鈦礦起源 6
1-3-2 鈣鈦礦太陽能電池發展 6
1-3-3 鈣鈦礦層及電洞傳輸層製備 7
1-3-3-1 旋轉塗佈法(Spin coating) ………………………………..7
1-3-3-2 刮刀塗佈法(Blade coating) ………………………………8
1-4 實驗動機 11
第二章 實驗方法 12
2-1 實驗藥品 12
2-2 實驗儀器 14
2-3 材料製備 15
2-3-1 二氧化鈦緻密層配製 15
2-3-2 二氧化鈦介孔層配製 15
2-3-3 鈣鈦礦溶液配製 15
2-3-4 電洞傳輸層溶液配製 16
2-4 正式(n-i-p)結構鈣鈦礦太陽能元件製作 16
2-4-1 FTO導電玻璃清洗 16
2-4-2 UV-ozone表面處理 17
2-4-3 電子傳輸層-二氧化鈦緻密層製備 17
2-4-4 電子傳輸層-二氧化鈦介孔層製備 17
2-4-5 旋轉塗佈法製備鈣鈦礦主動層 18
2-4-6 刮刀塗佈法製備鈣鈦礦主動層 19
2-4-7 旋轉塗佈法製備電洞傳輸層 20
2-4-8 刮刀塗佈法製備電洞傳輸層 20
2-4-9 蒸鍍銀電極 20
第三章 結果與討論 22
3-1基板溫度對刮塗電洞傳輸層之影響 22
3-1-1基板溫度對刮塗電洞傳輸溶液Spiro-OMeTAD之影響 22
3-1-2基板溫度對刮塗溶解性好的電洞傳輸溶液YKP03之影響 24
3-1-2-1 YKP03無摻雜(doping free) 條件電池效率表現 ……....24
3-1-2-2 YKP03無摻雜(doping free) 條件下之電池穩定性….. 26
3-1-2-3不同基板溫度下刮刀塗佈電洞傳輸層YKP03之表面形貌分析 …………………………………………………………….28
3-1-2-4 YKP03摻雜(doping) 條件電池效率表現 ……………...30
3-1-2-5 摻雜(doping)條件下之電池穩定性 …………………….32
3-1-3基板溫度對刮塗溶解性差的電洞傳輸溶液ZYW01之影響 34
3-2 刮刀與基板間隙(gap) 對刮塗電洞傳輸層之影響 37
3-3 旋轉塗佈製程與刮刀塗佈製程之比較 40
3-3-1 不同塗佈法對溶解性差的電洞傳輸溶液ZYW01之電池效率表現影響 40
3-3-2 不同塗佈法對電洞傳輸層之光電性質比較 44
3-3-2-1光激發螢光量測及分析 …………………………………44
3-3-2-2 時間解析螢光光譜(TRPL) ………………………..……47
3-3-3 不同塗佈法對電洞傳輸層之表面形貌影響 55
第四章 結論 60
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[43] 國立中央大學化材所,2020年王志遠之碩士論文指導教授 劉青原(Ching-Yuan Liu) 審核日期 2020-8-18 推文 facebook plurk twitter funp google live udn HD myshare reddit netvibes friend youpush delicious baidu 網路書籤 Google bookmarks del.icio.us hemidemi myshare