符合循環經濟概念之全固態可撓性超級電容器

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姓名

何祈恩(Chi-An Ho) 查詢紙本館藏

畢業系所

化學工程與材料工程學系

論文名稱

符合循環經濟概念之全固態可撓性超級電容器
(All Solid-states Flexible Supercapacitor Towards the Circular Economy)

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摘要(中)

本研究將循環經濟和仿生材料概念帶入超級電容的系統中，利用奈米複合材料其包含蒙脫土(MMT)、聚乙烯醇(PVA)、聚二氧乙基噻吩:聚苯乙烯磺酸(PEDOT:PSS)和二氧化釕(RuO2)奈米粒子，來製造環保全固態可撓式超級電容器。透過X光繞射、X光顯微術、掃描式電子顯微術、X光吸收光譜、力學測試、接觸角和電化學分析有系統探討此環保全固態可撓式超級電容器之結構-性質-性能之關係。其中，我們分別利用蒙脫土吸附釕金屬離子於層狀結構內的特性，透過方法A和B合成二氧化釕(RuO2)奈米粒子，而其奈米粒子尺寸與分布也分別導致蒙托土形成紙牌屋(House of card)結構以及仿珍珠貝 (Nacre-like)結構於電極內部。我們發現紙牌屋結構電極具有較好的電化學性能，但是其力學性質則稍差於仿珍珠貝結構電極。亦發現紙牌屋結構電極其電容值可達568 mF/cm2 (71F/g)，也優於過去文獻曾報導過RuO2全固態可撓式超級電容器。此外，其能量密度和電流密度分別為40.6 Wh/cm2 (10.2Wh/kg)和4 mW/cm2 (1000W/kg)。透過回收再製後之超級電容器其效能可達至原電容器之70%，成功落實了循環經濟之概念。

摘要(英)

In this study, we introduce two concepts of circular economy and biomimetic materials into nanocomposite electrodes for fabricating all-solid-state flexible supercapacitors (ssFSCs). The designed nanocomposites were composed of montmorillonite (MMT), ruthenium dioxide nanoparticles (RuO2 NPs), polyvinyl alcohol (PVA) and Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS). We investigated structure-property-performance relationships of the ECO-firendly all-solid-state flexible supercapacitor using X-ray diffraction, transmission X-ray microscope, X-ray absorption spectroscopy, electron microscope, testing machine, contact angle and potentiostat–galvanostat. Attributing to RuO2 NPs size and their distribution in the structural electrodes, a house-of-cards structure and a nacre-like structure were respectively obtained from synthesized method A and method B. We found that the house-of-cards structural ssFSC features higher performance of storage energy but lower mechanical strength than the nacre-like structural ssFSC. The capacitance of the house-of-cards ssFSC is up to 568 mF/cm2 (71 F/g), which is also better than the RuO2-based ssFSCs. Furthermore, their maximum energy and power densities are respectively calculated as 40.6 Wh/cm2 (10.2Wh/kg) and 4 mW/cm2 (1000W/kg). Concerning recycling of electrodes for the circular economy, storage energy performance of the recycled devices can perform about 70% of the original devices.

關鍵字(中)

★ 循環經濟
★ 全固態超級電容
★ 二氧化釕
★ 蒙托土
★ 紙牌屋
★ 仿貝

關鍵字(英)

★ PEDOT:PSS
★ House-of-cards
★ Nacre-like
★ All solid-states
★ supercapacitor

論文目次

摘要 I
ABSTRACT II
目錄 IV
圖目錄 VI
表目錄 IX
第一章緒論 1
1.1 前言 1
1.2 超級電容原理與種類 2
1.2.1 電雙層電容器 2
1.2.2 擬電容器 3
1.2.3 混合式超級電容 4
1.3 電化學儲能裝置 5
1.4 可撓性超級電容 6
1.5循環經濟 7
第二章研究動機及目的 9
2.1 電極設計與材料選擇 10
2.2 材料性質 12
2.2.1 聚二氧乙基噻吩:聚苯乙烯磺酸 (PEDOT:PSS) 12
2.2.2 蒙托土 (Montmorillonite, MMT) 14
2.2.3 聚乙烯醇 (Poly vinyl alcohol,PVA) 15
第三章實驗儀器以及藥品 16
3.1 實驗儀器 16
3.1.1 定電位–定電流儀 (Potentiostat–Galvanostat) 16
3.2 同步輻射先進光源應用 16
3.2.1 X光繞射儀 (X-ray Diffraction, XRD) 17
3.2.2 穿透式X光顯微技術 (Transmission X-ray Microscope, TXM) 17
3.2.3 X光吸收光譜 (X-ray Absorption Spectroscopy, XAS) 18
3.3 實驗藥品與器具 20
3.3.1蒙脫土(Montmorillonite) 20
3.3.2導電高分子(PEDOT:PSS) 20
3.3.3聚乙烯醇 (Polyal vinyl alcohol, PVA) 20
3.3.4二三氟甲基磺醯亞胺鋰 (Bis(trifluoromethane) sulfonamide lithium salt) 20
3.3.5氯化釕(III)水合物 20
3.3.6 硫酸 20
3.3.7 異丙醇 21
3.3.8 高壓釜 21
第四章樣品製備與實驗流程 22
4.1 二氧化釕/蒙脫土複合材 (RUO2 /MMT) 22
4.2 電極製作 23
4.3 電解質配製 23
4.4 超級電容裝置製作 24
4.5 回收之超級電容並重新製備 24
第五章實驗結果與討論 25
5.1 RUO2/MMT可撓電極之結構鑑定 25
5.1.1 紙牌屋結構與仿貝結構 26
5.2 RUO2/MMT/PEDOT:PSS(STEC)/PVA電極之物理性質測試 33
5.2.1 應力與應變 33
5.2.2 扭力測試 35
5.2.3 耐水性測試 37
5.3.4 導電度 40
5.3 RUO2/MMT電容器之電化學測試 42
5.3.1 RuO2/MMT電極之電化學測試 42
5.3.2 RuO2/MMT電容器 44
5.3.3 臨場快速X光吸收光譜 46
5.3.4 酸洗處理之RuO2/MMT電容器 48
5.4 RUO2/MMT電容器之電極回收 51
第六章結論 56
第七章參考資料 57

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指導教授

孫亞賢(Ya-Sen Sun)

審核日期

2020-8-18

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