自製光觸媒催化材料應用於去除 甲苯之可行性研究

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杜侑倫(Yu-Lun Tu) 查詢紙本館藏

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論文名稱

自製光觸媒催化材料應用於去除甲苯之可行性研究
(Feasibility study on removal of toluene by prepared air-purifying photocatalyst)

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至系統瀏覽論文 (2026-6-1以後開放)

摘要(中)

本研究嘗試結合高壓蒸氣技術(控制蒸氣壓力0.9 MPa、蒸氣溫度190 °C、反應時間8小時)及奈米二氧化鈦塗層技術，評估漿紙污泥煅燒灰製備為輕質化光觸媒催化材料之可行性。為驗證光觸媒催化之功能特性，除進行材料之特性分析外，並以模擬空氣淨化試驗，評估其去除甲苯之能力。輕質化材料試驗結果顯示，在鈣矽比(CaO/SiO2)控制在1.11及調濕養護之條件下，材料特性除符合輕質化材料之體密度(1.07 g/cm3)及視孔隙率(57.13%)之要求外，材料之抗壓強度可達57 kg/cm2以上，符合相關高壓蒸氣養護輕質氣泡混凝土之產品規範。光觸媒材料之主要晶相，係以鈣矽水合物(C-S-H)、方解石(Calcite, CaCO3)、勃姆石(Boehmite, AlO(OH))及矽酸鈣(Ca2SiO4)等為主。空氣淨化試驗結果顯示，相較於未塗佈TiO2之材料，塗佈0.5%、1.0%及1.5% TiO2之光觸媒材料，具較佳之光催化活性，其中尤以1.0% TiO2之光觸媒材料，具最佳之光催化活性及耐久性，就CO2礦化率而言，可達81.88%，然經五次重複試驗後，礦化率降低至3.59%。本研究以漿紙污泥煅燒灰製備輕質化材料，於表面塗佈二氧化鈦後，初步驗證可藉由光催化特性將甲苯轉換為二氧化碳。整體而言，本研究雖具後續應用發展之潛力，然未來仍需進一步探討與評估甲苯之去除反應機制，以釐清自製輕質化光觸媒催化材料之應用可行性。

摘要(英)

This study investigates the characterization of air-purifying photocatalyst lightweight material manufactured by paper mill sludge calcined ash by combination of autoclaving technique (steam pressure 0.9 MPa, steam temperature 190 °C, and reaction time 8 hours) and nano-titanium dioxide (TiO2) coating technology. In order to evaluate the catalytic ability of prepared air-purifying photocatalyst, the toluene removal experiments were also conducted.
In the case of CaO/SiO2 ratio 1.11 and curing by humidity control, the experimental results indicated that the lightweight material has not only met the criteria of relevant autoclaving lightweight material with bulk density (1.07 g/cm3) and apparent porosity (57.13%), but also has the good performance of compressive strength (higher than 57 kg/cm2).The mainly crystal phases of the lightweight material were identified by XRD including calcium silicon hydrate (C-S-H), Calcite(CaCO3), Boehmite(AlO(OH)), and Ca2SiO4. According to the analysis results of the air purification test, the prepared catalysts containing 0.5%, 1.0%, and 1.5% TiO2 have a good photocatalytic characteristics. Especially for 1.0% TiO2 air-purifying photocatalyst, it presents the best photocatalytic activity with corresponding to 81.88% of CO2 mineralization rate. On the other hand, the prepared catalyst durability seems not to be good enough. After five cycles, the CO2 mineralization rate was decreased to 3.59%. In this study, the prepared air-purifying photocatalyst could provide the good photocatalytic characteristics to convert toluene into CO2. Although the prepared air-purifying photocatalyst have a good potential for application; however, to clarify the long-term application and market development of air-purifying photocatalyst lightweight material, it is necessary to further discuss and evaluate the toluene removal mechanism in the future.

關鍵字(中)

★ 光觸媒催化材料
★ 高壓蒸氣技術
★ 漿紙污泥
★ 二氧化鈦

關鍵字(英)

★ air-purifying photocatalyst
★ autoclaving
★ paper mill sludge
★ titanium dioxide

論文目次

摘要 i
Abstract iii
誌謝 v
目錄 vii
圖目錄 ix
表目錄 ix
第一章前言 1
第二章文獻回顧 5
2-1漿紙污泥之處理現況 5
2-1-1漿紙污泥及漿紙污泥灰產量及處理現況 5
2-1-2漿紙污泥及漿紙污泥灰之物化特性 8
2-2高壓蒸氣技術之原理機制與應用 13
2-2-1高壓蒸氣技術之原理機制 13
2-2-2操作條件及鈣矽比對材料之影響 14
2-2-3高壓蒸氣技術研究與應用 17
2-2-4國內廢棄物轉換為材料之相關研究 24
2-3光催化氧化處理室內空氣污染物 27
2-3-1室內空氣污染物之來源及危害 27
2-3-2二氧化鈦光催化氧化原理機制 29
2-3-3光催化氧化甲苯之反應途徑及副產物 34
2-3-4光催化氧化不同參數對去除效率的影響 38
2-3-5光催化材料去除VOCs的應用 47
2-3-6光催化材料去除NOx及其他應用 56
第三章研究材料與方法 63
3-1實驗材料 63
3-2實驗操作條件 64
3-2-1預先試驗 64
3-2-2塗佈TiO2試驗 65
3-2-3空氣淨化試驗 66
3-2-4實驗設備 68
3-3實驗方法與分析項目 73
第四章結果與討論 77
4-1研究材料基本特性分析 77
4-1-1漿紙污泥及煅燒灰之化學組成 77
4-1-2煅燒灰之粒徑分析 79
4-1-3漿紙污泥及煅燒灰熱重損失之分析結果 80
4-1-4煅燒灰之物種鑑定及微觀結構 81
4-2光觸媒催化材料之特性分析 83
4-2-1預先試驗分析結果 83
4-2-2材料之晶相物種鑑定 85
4-2-3材料之紅外線光譜分析結果 86
4-2-4二氧化鈦塗層之均勻性及微觀結構 88
4-3光觸媒催化材料去除甲苯之可行性 92
4-3-1空白試驗 92
4-3-2二氧化鈦含量對甲苯降解效率之影響 93
4-3-3材料之重複性試驗 99
4-3-4光催化反應後材料之晶相物種及微觀結構 103
第五章結論與建議 109
5-1結論 109
5-2建議 111
參考文獻 113

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指導教授

江康鈺(Kung-Yuh Chiang)

審核日期

2021-6-2

推文