博碩士論文 109326011 詳細資訊




以作者查詢圖書館館藏 以作者查詢臺灣博碩士 以作者查詢全國書目 勘誤回報 、線上人數:23 、訪客IP:3.144.244.117
姓名 蔡承桓(Cheng-Huan Tsai)  查詢紙本館藏   畢業系所 環境工程研究所
論文名稱 反向電透析(RED)產電效能評估 -以濃度、流速、膜對數及流道厚度為操作參數
(Evaluation of concentration, space velocity, cell pairs and channel thickness for power generation by Reverse Electrodialysis(RED))
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檔案 [Endnote RIS 格式]    [Bibtex 格式]    [相關文章]   [文章引用]   [完整記錄]   [館藏目錄]   至系統瀏覽論文 (2026-2-1以後開放)
摘要(中) 本研究是目前台灣少數投入於反向電透析(Reverse electrodialysis,RED)之研究,為國內發展新型可再生能源有著重要貢獻,能源議題是國際間重要議題,發展可再生能源替代傳統化石能源以降低二氧化碳(CO2)排放相當重要。藍色能源(blue energy)是存在於海洋之可再生能源,包含波浪、潮汐、鹽差能等,鹽差能是其中能源獲取效率最高者,而RED是用於收集鹽差能最有效的方法,RED原理是利用交錯排列陰陽離子交換膜形成隔室並通入濃、淡鹽水,鹽水因濃度梯度(salinity gradient)形成離子流,經過陰陽極反應後形成電流再經由外部電路收集。根據研究,傳統化石能源碳排放為1,004 g CO2/kWh(燃煤)、543 g CO2/kWh(天然氣),RED收集之鹽差能碳排放為<10 g CO2/kWh,相較之下RED於碳排放減量上具有良好的競爭力。影響RED發電之因素眾多,包含溶液條件(濃度、種類、流速等)、離子交換膜條件、電極系統條件等,本研究主要利用5對10 x 20 cm2之RED系統進行實驗,針對不同RED操作條件,如濃、淡水濃度、流速與離子交換膜對數及流道厚度四項參數進行比較。在維持所有條件下僅提升濃水濃度或降低淡水濃度,對於RED系統之電壓及功率有幫助,但過高之濃水取得有限、過低之淡水導電率下降反而可能導致最終功率下降,經過評估顯示較佳之濃水、淡水濃度應介於1 ~ 2.5 M NaCl、0.02 ~ 0.05 M NaCl,濃度比則應高於50:1;溶液流速快慢會影響離子交換效率及RED系統電阻,其中淡水流速快慢影響較濃水高,在RED系統整體流速增加時,RED發電之功率呈現先下降後上升,在泵能耗納入考量後,以濃、淡水空間流速0.25、0.25 1/min(流量47.5、47.5 mL/min)可以得到較佳之功率密度(0.328 W/m2);離子交換膜對數則影響RED系統之電壓,在未來實際投入實廠之RED系統必須盡可能增加膜對數以獲取更高效率之能源產生;流道厚度則主要影響RED系統之電阻,當厚度達到4 mm,電阻上升至約11 Ω,將大幅降低RED系統之發電效率,然而厚度過小亦可能造成流道製作過程困難,在厚度之設計上應介於1 mm左右。本實驗主要提供了目前國內首個實驗室級RED系統之操作參數建立,以提供後續研究之參考依據。
摘要(英) This research is currently one of a few research in Taiwan that has focused on reverse electrodialysis (RED), which has made an important contribution to the development of renewable energy in Taiwan. Energy issues are important international issues, and the development of renewable energy to replace traditional fossil fuel to reduce carbon dioxide (CO2) emissions are extremely important. Blue energy is a renewable energy that only exists in the ocean, including waves, tides, and salinity gradient power (SGD). Salinity gradient energy is the most efficient energy source among them, and RED is the most effective way to collect energy. The fundamental mechanism of RED is to use staggered anion and cation exchange membranes to form compartments that concentrated and dilute salt water can flow through respectively. The salty water forms an ion flow due to the concentration gradient, a current is formed after the redox reactions, and then collected by an external circuit. According to the previous research, the carbon emission of traditional fossil fuel is 1004 g CO2/kWh for coal and 543 g CO2/kWh for natural gas. On the other hand, the carbon emission of salt gradient energy collected by RED is <10 g CO2/kWh. It has good competitiveness in terms of emission reduction. There are several factors affecting RED power generation, including solution conditions (concentration, type, flow rate, etc.), ion exchange membrane conditions, electrode system conditions, etc. This study mainly uses 5 pairs of 10 x 20 cm2 RED systems to conduct experiments. Various concentrations, space velocity, cell pairs and channel thickness are applied to compare the efficiency of power generation. Evaluation shows that the concentration of concentrated water and dilute water should be between 1 ~ 2.5 M NaCl and 0.02 ~ 0.05 M NaCl, and the concentration ratio should be higher than 50 : 1. The velocity of the solution affects the ion exchange efficiency and the resistance of the RED system. The velocity of the dilute water is higher than that of the concentrated water. When the overall flow rate of the RED system increases, the power of the RED power generation decreases first and then increases. After the pump energy consumption is taken into consideration. The better power density (0.328 W/m2) can be obtained with space velocity of 0.25-0.25 1/min (flow rate of 47.5, 47.5 mL/min). The cell pairs of RED system must be increased as much as possible to obtain more efficient energy generation. The thickness of the channel mainly affects the resistance of the RED system. The thickness design should be around 1 mm. This experiment mainly provides the establishment of the operating parameters of the first laboratory-level RED system in Taiwan, so as to provide a reference for follow-up research.
關鍵字(中) ★ 反向電透析
★ 濃度梯度
★ 可再生能源
★ 碳排放
關鍵字(英) ★ reverse electrodialysis
★ salinity gradient power
★ renewable energy
★ carbon emission
論文目次 摘 要 I
ABSTRACT II
致 謝 IV
目 錄 V
圖目錄 VIII
表目錄 X
第一章 前言 1
1.1 研究緣起 1
1.2 研究目的 3
第二章 文獻回顧 4
2.1 反向電透析 4
2.1.1 反向電透析原理 4
2.1.2 反向電透析公式推導 6
2.1.3 影響RED產電效率之因素 8
2.1.3.1 進料溶液特性 8
2.1.3.2 離子交換膜特性 10
2.1.3.3 電極系統 13
2.1.4 RED實際案例 15
2.1.5 研究應用 16
2.2 溫室效應 18
2.2.1 溫室效應 18
2.2.2 溫室效應潛勢 19
2.2.3 減碳政策 20
2.2.4 各項綠色能源發展近況 21
2.2.5 綠色能源碳排放 28
第三章 研究方法 29
3.1 實驗流程與架構 29
3.2 實驗材料與設備 30
3.2.1 實驗藥品 30
3.2.2 實驗設備 31
3.3 實驗方法 33
3.3.1 濃度影響測試 33
3.3.2 流速影響測試 34
3.3.3 離子交換膜對數影響測試 35
3.3.4 流道厚度影響測試 35
3.4 測試儀器與原理 36
3.4.1 導電度計 36
3.4.2 恆電位儀 37
第四章 結果與討論 39
4.1 濃度影響分析 39
4.1.1 淡水濃度影響 39
4.1.2 濃水濃度影響 41
4.2 流速影響分析 47
4.2.1 淡水流速影響 47
4.2.2 濃水流速影響 49
4.2.3 相同流速比、不同流速影響 51
4.3 離子交換膜對數影響 53
4.4 流道厚度影響 55
4.5 產電效能比較 57
第五章 結論與建議 59
5.1 結 論 59
5.2 建議 61
參考文獻 64

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指導教授 林伯勳(Po-Hsun Lin) 審核日期 2023-1-18
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