層狀奈米材料之介面開發應用於奈米發電機設計

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姓名

蔡智鈞(Tsai Chih-Chun) 查詢紙本館藏

畢業系所

化學工程與材料工程學系

論文名稱

層狀奈米材料之介面開發應用於奈米發電機設計
(Interfacial Development of Layered Nanomaterials for Advanced Nanogenerator Design)

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至系統瀏覽論文 (2029-11-18以後開放)

摘要(中)

奈米材料之介面設計可創造優異的電荷轉移途徑和高效的電荷分離效應，已廣泛應用於光催化、有機染料吸附、超級電容器和太陽能電池等各個研究領域。然而，在摩擦起電領域中的應用則尚未被有效探索。在此工作中，我們成功以低維度奈米材料為基礎進行新穎介面設計，並藉由原子力顯微鏡技術來探索其介面特性。後續我們也實際將此結構導入製作成摩擦起電元件。由結果發現，以新穎介面進行設計之起電元件，可輸出電壓、電流、電荷分別為 140 V、1750 nA、38 nC，相較於未加入之系統，表現增強了四倍之多，說明了此介面設計應用於摩擦起電方面的極大潛力。

摘要(英)

Interfacial design of nanomaterials has been renowned for their excellent charge transfer pathways and efficient charge separation, leading to widespread applications in fields such as photocatalysis, organic dye adsorption, supercapacitors, and solar cells. However, their applications in the field of triboelectricity have yet to be effectively explored. In this work, we successfully designed a new interface based on low dimensional nanomaterials and investigated their properties using atomic force microscopy. Subsequently, we incorporated this structure into a triboelectric device. The results revealed that the device designed with this new interface can achieve output values of 140 V for voltage, 1750 nA for current, and 38 nC for charge, representing a fourfold increase compared to the control group. This demonstrates the significant potential of this interfacial design in triboelectric applications.

關鍵字(中)

★ 層狀奈米材料

關鍵字(英)

★ Nanomaterials

論文目次

摘要 i
Abstract ii
目錄 iii
圖目錄 vi
表目錄 viii
第一章緒論 1
第二章文獻回顧與探討 2
2-1 摩擦起電現象 2
2-1-1 摩擦起電效應 3
2-2 摩擦起電效應的量化 4
2-2-1 結合原子力顯微鏡和掃描凱文探針顯微鏡量化摩擦起電 5
2-3 摩擦起電材料序列 6
2-4 范德格拉夫發電機 (Van de Graff generator) 7
2-5 摩擦起電奈米發電機介紹 8
2-5-1 工作模式 8
2-5-2 TENG的位移電流 10
2-6 發展領域 11
2-7 摩擦起電奈米發電機基本結構設計 12
2-7-1 間隔結構 12
2-7-2 拱型結構 13
2-7-3 三明治結構 13
2-7-4 多層集結結構 14
2-7-5 可拉伸性結構 14
2-8 奈米材料在摩擦起電奈米發電機所扮演的角色 15
2-8-1 奈米材料在摩擦起電奈米發電機的應用 16
2-8-2 奈米材料介面設計 18
2-9 新穎結構設計之摩擦起電奈米發電機 19
2-10 多功能摩擦起電奈米發電機設計 19
2-10-1 防水織物摩擦起電奈米發電機 20
2-10-2 具有氣體感測功能之摩擦起電奈米發電機 21
第三章實驗方法 22
3-1製程方法選擇 22
3-2 材料合成與摩擦起電奈米發電機製作 22
3-3 材料鑑定儀器 24
3-3-1 X光繞射儀 24
3-3-2 拉曼光譜 25
3-3-3 掃描式電子顯微鏡 26
3-3-4 X射線光電子能譜學分析 29
3-3-5 紫外光電子能譜學分析 30
第四章結果與討論 31
4-1 材料分析鑑定 31
4-1-1 X光繞射分析 (XRD) 31
4-1-2 拉曼光譜鑑定 (Raman) 32
4-1-3 掃描式電子顯微鏡 (SEM) 33
4-1-4 能量色散X色線譜分析 (EDS) 34
4-1-5 X射線光電子能譜學分析 (XPS) 35
4-1-6 紫外光電子能譜學分析 (UPS) 37
4-2 表面電位 39
4-3 介電量測 40
4-4電性量測 41
第五章結論與未來展望 44

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指導教授

吳子嘉(Albert T. Wu)

審核日期

2024-11-18

推文