Ti/Fe比與合金元素(Mn,Ni)對於Ti-Fe儲氫合金吸放氫特性之影響

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姓名

唐瑋(Wei Tang) 查詢紙本館藏

畢業系所

機械工程學系

論文名稱

Ti/Fe比與合金元素(Mn,Ni)對於Ti-Fe儲氫合金吸放氫特性之影響
(Effect of the Ti/Fe ratio and element M(M=Mn,Ni)substitution on hydrogen storage properties of Ti-Fe alloys)

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摘要(中)

本研究以真空電弧熔煉法製備TixFe(1-y)My(M=Mn,Ni)系列合金，藉由微結構觀察與儲氫特性測量，探討不同Ti/Fe比與合金元素Mn、Ni對於儲氫性質之影響。結果顯示提升Ti/Fe比可改善合金活化特性與儲氫量，Ti1.1Fe的有效放氫量為1.54 wt%，是Ti-Fe二元合金中有效放氫量最佳之組成。當Mn的添加不超過12wt%時，有助於提升Ti1.1Fe(1-x)Mnx合金活化特性與有效放氫量。其Ti1.1Fe0.75Mn0.25合金有效放氫量為1.54 wt%。Ti1.1Fe0.75Mn0.25合金隨Ni含量增加，合金中各項儲氫性質皆下降。以活化特性、動力學性質、有效放氫量與遲滯行為各項儲氫特性作比較，Ti1.1Fe0.75Mn0.25為此一系列合金最佳成分。

摘要(英)

This research plans to utilize arc-melted method to prepare TixFe(1-y)My (M=Mn,Ni) alloys,and then studies the effect of the Ti/Fe ratio and element M(M=Mn,Ni) substitution on Ti-Fe alloys of hydrogen storage properties with different microstructure.It was found that increasing of Ti/Fe ratio could improve activation characteristics and effective hydrogen content.The best effective hydrogen storage capacity of Ti-Fe binary is 1.54wt% and its composition is Ti1.1Fe.The activation characteristics and hydrogen desorption capacity was improved when Mn contained less than 12 wt%. The best effective hydrogen storage capacity of Ti1.1Fe0.75Mn0.25 alloy is 1.54 wt%.The hydrogenation properties got worse with increasing of Ni content in Ti1.1Fe0.75Mn0.25 alloy. In consideration of activation properties, kinetics, effective capacity and hysteresis characteristics, Ti1.1Fe0.75Mn0.25 alloy is the best composition in this study.

關鍵字(中)

★ 儲氫合金
★ β-Ti相
★ Ti-Fe合金

關鍵字(英)

★ β-Ti phase
★ Hydrogen storage material
★ Ti-Fe alloys

論文目次

一、前言與文獻回顧……………………………………………………1
1-1 儲氫合金發展簡介……………………………………………1
1-2 儲氫合金種類…………………………………………………2
1-3 儲氫合金吸放氫特性…………………………………………3
1-3-1 吸放氫動力學性質……………………………………3
1-3-2 熱力學性質……………………………………………4
1-4 Ti系列儲氫合金簡介…………………………………………8
1-4-1合金元素對鈦基儲氫合金吸放氫平台性質之影響…8
1-4-2鈦基AB型TiFe儲氫合金………………………………9
1-4-3 Laves相AB2型TiM2儲氫合金………………………12
1-4-4 BCC固溶型TiV2 儲氫合金…………………………13
1-5 研究背景與目的……………………………………………16
二、實驗方法與步驟…………………………………………………18
2-1實驗方法與流程………………………………………………18
2-2儲氫合金置備流程……………………………………………19
2-3感應耦合電漿質譜儀(Inductively coupled plasma-
mass spectrometry)成分分析……………………………20
2-4 X光粉末繞射分析……………………………………………21
2-5微結構分析……………………………………………………21
2-4-1 金相觀察 (OM)………………………………………21
2-4-2 電子微探儀分析 (EPMA)……………………………21
2-6合金儲放氫特性測試…………………………………………22
2-7熱程控脫附儀分析(TPD)……………………………………22
三、結果與討論………………………………………………………23
3-1 不同Ti/Fe比對於TiFe合金吸放氫性質之研究……………23
3-1-1 合金結構分析………………………………………23
3-1-2 儲放氫特性分析……………………………………27
3-1-2-1 活化測試……………………………………27
3-1-2-2吸放氫動力學測試…………………………29
3-1-2-3 PCI曲線量測………………………………32
3-1-3 熱程控脫附儀分析…………………………………34
3-2 Mn含量對於TiFe合金吸放氫性質之研究…………………37
3-2-1 合金結構分析………………………………………37
3-2-2 合金儲放氫性質測試………………………………40
3-2-2-1 活化測試……………………………………40
3-2-2-2 吸放氫動力學測試…………………………41
3-2-2-3 PCI曲線測試………………………………43
3-3 Ni含量對於TiFe合金吸放氫性質之研究…………………45
3-3-1 合金結構分析………………………………………45
3-3-2 合金儲放氫性質測試………………………………48
3-3-2-1 吸氫動力學測試……………………………48
3-3-2-2 PCI曲線測試………………………………50
四、結論………………………………………………………………52
五、未來工作…………………………………………………………53
六、參考文獻…………………………………………………………54

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指導教授

李勝隆(Sheng-long Lee)

審核日期

2010-7-22

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