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姓名 李浚瑀(Jyun-yu Li) 查詢紙本館藏 畢業系所 化學工程與材料工程學系 論文名稱 以懸浮聚合法製備潤滑油微膠囊材料
(microcapsulation of lubricating oil by suspension polymerization)相關論文 檔案 [Endnote RIS 格式]
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摘要(中) 本論文利用懸浮聚合法製備電鍍共沉積用之潤滑油微膠囊，將單體、
交聯劑、潤滑油和起始劑混合，加入含有穩定劑PVA 的水溶液中，以
乳化均質機攪拌均勻後進行懸浮聚合反應，進而製備潤滑油微膠囊材料。
本實驗使用的單體為甲基丙烯酸甲酯(MMA)、苯乙烯(St)，交聯劑為二甲基
丙烯酸乙二醇酯(EGDMA)和起始劑偶氮二異丁腈(AIBN)。
本研究探討穩定劑濃度、單體比例、起始劑添加量、交聯劑濃度、
均質機轉速、反應時間和潤滑油的添加量等不同條件對微膠囊材料的整
體轉化率、潤滑油含量、潤滑油產率、高分子產率、包覆效率及外觀的
影響，並利用熱重損失分析儀(TGA)、傅立葉轉換紅外線光譜儀(FTIR)、
掃描式電子顯微鏡(SEM)和動態光散射儀(DLS)進行分析。
從本研究中可得知，當穩定劑PVA 濃度為0.1wt%時有最佳微膠囊
外觀，St 的單體比例為50%以上時較適合作為微膠囊殼層，起始劑添加
量和交聯劑濃度的上升有助於提升整體轉化率和高分子產率，反應時間為
6 和8 小時有較佳的潤滑油含量和產率。
本研究可製備出潤滑油含量為63.4%，粒徑範圍約為150~350nm，
以及整體轉化率為71.2%之潤滑油微膠囊材料。
摘要(英) Microcapsulation of lubricating oil for electrolytic co-deposition has been
developed by suspension polymerization. Monomers, cross-linking agent,
lubricating oil, and initiator were mixed and then added to the water phase
including stabilizer, PVA. After that, the solution was homogenized and
proceeded to suspension polymerization at 70oC. Methyl methacrylate (MMA)
and styrene (St) were used as the monomers. Ethylene Glycol Dimethacrylate
(EGDMA) was used as cross-linking agent. Azobisisobutyronitrile (AIBN) was
used as initiator.
In this study, different parameters, the concentrations of stabilizer, initiator,
cross-linking agent, and lubricating oil, homogenized speed, reaction time, and
addition of lubricating oil were discussed. Thermo gravimetric Analysis (TGA),
Scanning Electron Microscope (SEM) Fourier-Transform Infrared Spectrometer
(FTIR), Dynamic light scattering (DLS) were used to determine the
characterization of the microcapsules.
The results showed that the morphology of microcapsules could be
improved by adding 0.1wt% of stabilizer. The weight fraction of St in monomers
more than or equal to 50% was more suitable to be the shell materials. As the
amount of initiator and cross-linking agent increased, the total conversion and
polymer yield would increase. When reaction time was 6 or 8 hours, there are
better lubricating oil content and yield.
The best results of microcapsules showed that the lubricating oil content is
63.4%, the range of particle size is from 150 to 350nm, and the total conversion is 71.2%.
關鍵字(中) ★ 微膠囊
★ 懸浮聚合法
★ 潤滑油
★ 苯乙烯
★ 甲基丙烯酸甲酯關鍵字(英) ★ microcapsules
★ suspension polymerization
★ styrene
★ methyl methacrylate
★ lubricating oil論文目次 摘要 ........................................................................................................................ i
Abstract ................................................................................................................. ii
致謝 ...................................................................................................................... iv
目錄 ....................................................................................................................... v
圖目錄 ................................................................................................................ viii
表目錄 ................................................................................................................. xii
第一章 緒論 ......................................................................................................... 1
1-1 電鍍共沉積表面改質 .............................................................................. 1
1-2 微膠囊化技術 ......................................................................................... 4
1-3 微膠囊化方法 ......................................................................................... 5
(1) 物理化學法： .................................................................................. 5
a.凝膠法............................................................................................ 5
b.乳化溶劑揮發法 ........................................................................... 6
(2) 化學方法： ...................................................................................... 6
a.原位聚合法 ................................................................................... 6
b.界面聚合法 ................................................................................... 6
c.懸浮聚合法 ................................................................................... 7
(3) 機械方法： ...................................................................................... 7
a.噴霧乾燥法 ................................................................................... 7
1-4 研究動機及目的 ..................................................................................... 8
第二章 實驗 ......................................................................................................... 9
2-1 實驗藥品 ................................................................................................. 9
2-2 實驗儀器 ............................................................................................... 10
2-3 以懸浮聚合法製備潤滑油微膠囊材料 .............................................. 11
2-4 潤滑油微膠囊之物性測試 ................................................................... 13
2-4-1 熱重損失分析儀(TGA) ............................................................. 13
2-4-2 傅立葉轉換紅外線光譜儀(FTIR) ............................................. 13
2-4-3 掃描式電子顯微鏡(SEM) ......................................................... 13
2-4-4 動態光散射儀(DLS) .................................................................. 13
第三章 結果與討論 ........................................................................................... 14
3-1 以懸浮聚合法製備潤滑油微膠囊 ...................................................... 14
3-1-1 穩定劑濃度對微膠囊之影響 ................................................. 14
3-1-2 單體比例對微膠囊之影響 ..................................................... 24
3-1-3 起始劑添加量對微膠囊之影響 ............................................ 30
3-1-4 交聯劑濃度對微膠囊之影響 ................................................. 36
3-1-5 均質機轉速對微膠囊之影響 ................................................. 42
3-1-6 反應時間對微膠囊之影響 ..................................................... 48
3-1-7 潤滑油添加量對微膠囊之影響 ............................................ 54
3-1-8 最佳製備條件探討 .................................................................. 60
3-2 潤滑油和微膠囊的其它性質和比較 .............................................. 68
3-2-1 異丙醇清洗次數和潤滑油含量的關係 .................................... 68
3-2-2 懸浮聚合法和本體聚合法比較 ................................................ 71
3-2-3 傅立葉轉換紅外線光譜分析 .................................................... 74
3-2-4 動態光散射儀測量粒徑分析 .................................................... 76
第四章 結論 ....................................................................................................... 77
參考文獻 ............................................................................................................. 79
參考文獻 [1] K. Kondo, A. Ohgishi, Z. Tanaka, Electrodeposited Zn–TiO2 nanocomposite coatings and their corrosion behavior, J Electrochem Soc, 147 (2000) 2611
[2] K.I. Popov, N.V. Krstajic, M.I.Cekerevac, The mechanism of formation of coarse and disperse electrodeposits,Modern, Aspects of Electrochemistry, 30 (1996) 261–311
[3] M. Rosso, E. Chassaing, V. Fleury, J.-N. Chazalviel, Shape evolution of metals electrodeposited from binary electrolytes, J. Electroanal. Chem. , 559 (2003) 165–173
[4] V. Fleury, D. Barkey, Branched copper electrodeposition on a substrate, Physica A, 233 (1996) 730–741.
[5] N.D. Nikolic, K.I. Popov, Lj.J. Pavlovic, M.G. Pavlovic, J., Determination of critical conditions for the formation of electrodeposited copper structures suitable for electrodes in electrochemical devices, Electroanal. Chem. , 588 (2006) 88–98.
[6] N.D. Nikolic, K.I. Popov, Lj.J. Pavlovic, M.G. Pavlovic, Morphologies of copper deposits obtained by the electrodeposition at high overpotentials, Surf. Coat. Technol. , 201 (2006) 560–566.
[7] N.D. Nikolic, K.I. Popov, Lj.J. Pavlovic, M.G. Pavlovic, Phenomenology of a formation of a honeycomb-like structure during copper electrodeposition J. Solid State Electrochem. , 11 (2007) 667–675.
[8] K.I. Popov, S.S. Djokic, B.N. Grgur, Fundamental Aspects of Electrometallurgy, Kluwer Academic/Plenum Publisher, (2002)
[9] T. J. Tuaweri, G. D. Wilcox, Behaviour of Zn-SiO electrodeposition in the presence of N,N-dimethyldodecylamine, Surf Coat Technol, 200 (2006) 5921
[10] B. M. Praveen, T. V. Venkatesha, Electrodeposition and properties of Zn-nanosized TiO2 composite coatings, Appl Surf Sci, 254 (2008) 2418
[11] O. Satoshi, N. Hiroaki, K. Shigeo, A. Tetsuya, F. Hisaaki, O. Kazuo, Electrodeposition of Zn-Al2O3 Composite from Non-Suspended Solution Containing Quaternary Ammonium Salt, J Surf Finish Soc Japan, 53 (2002) 920
[12] 李國英，複合電鍍基本原理，材料及其製品表面加工新技術 (2002)
[13] B. M. Praveen, T. V. Venkatesha, Electrodeposition and properties of Zn-nanosized TiO2 composite coatings, Appl Surf Sci, 254 (2008) 2418
[14] M. Ghorbani, M. Mazaheri, K. Khanogholi, Y. Kharazi, Electrodeposition of graphite-brass composite coatings and characterization of the tribological properties, Surf. Coat. Technol. 148 (2001) 71.
[15] J.L. Stojak, J.B. Talbot, J., Investigation of electrocodeposition using a rotating cylinder electrode, Electrochem Soc, 146 (1999) 4504
[16] F. Linder, A. Feltz, J. Eur., Electrophoretic deposition - a method for preparation of semiconducting oxide ceramic layers, Ceram. Soc. 11 (1993) 269.
[17] P. Sarkar, et al., Fabrication of textured Bi‐Sr‐Ca‐Cu‐O thick film by electrophoretic deposition, J. Appl. Phys. 69 (1991) 1775.
[18] 朱立群，適合複合共沉積用的液體微膠囊製備研究，功能材料， 39 (2008) 1507-1510
[19] M Pushpavanam, N A ricalagan, N Srinivasan, P Santhakumar and S Suresh. Electrodeposited Ni-PTFE dry Lubricant Coating [J]. Plating & Surface Finishing (1996) 72-75
[20] 陳煜，成旦紅，金屬微膠囊螢光複合鍍層，電鍍與精飾，第四期，(2003)
[21] 王廣遠，微膠囊技術在複合鍍層中的應用，電鍍與精飾，第十三卷，第六期，(1991) 11-16
[22] 鄭天亮，含液體微膠囊複合鍍鎳、銅層的耐腐蝕性能研究，航空學報，第二十七卷，第一期，(2006) 147-151
[23] Alkan C, Sari A, Karaipekli A, Preparation, thermal properties and thermal reliability of microencapsulated n-eicosane as novel phase change material for thermal energy storage. Energ Convers Manage, 52(2011)1:687-692.
[24] 徐宏興，張志鵬，W/O 型苯乙烯微膠囊製放性之研究，華岡紡織期刊，第十卷，第二期，(2003) 134-139
[25] 張鴻奇，微膠囊技術之發展與應用回顧，化工資訊月刊，第十五卷，第八期
[26] B. K. Green and L. Schleicher, U. S. Patent (1956) 2,730, 456
[27] B. K. Green and L. Schleicher, U. S. Patent (1956) 2,730, 457
[28] J. Lazko et al., Soy glycinin microcapsules by simple coacervation method, Colloids and Surfaces, 37 (2004) 1–8
[29] B. Mohanty and H. B. Bohidar, Systematic of Alcohol-Induced Simple Coacervation in Aqueous Gelatin Solutions, Biomacromolecules, 4 (2003) 1080-1086
[30] Ka Zhang, Synthesis and release studies of microalgal oil-containing microcapsules prepared by complex coacervation, Colloids and Surfaces
[31] M. Morishita, Y. Inaba, M. Fukushima, S. Kobari, A. Nagata, J. Abe, Preparation of microcapsules, U.S. Patent, (1976) 3,943,063
[32] 蔡燕鈴，「含水溶性藥物之乙基纖維素微膠囊的製備」，國立中央大學化學工程與材料工程學系碩士論文 (2000)
[33] Fan YF, Zhang XX, Wang XC, Li J, Zhu QB, Super-cooling prevention of microencapsulated phase change material, Thermochim Acta, 413 (2004) 1-6.
[34] Fan YF, Zhang XX, Wu SZ, Wang XC, Thermal stability and permeability of microencapsulated n-octadecane and cyclohexane, Thermochim Acta, 429 (2005) 25-29.
[35] Zhang XX, Fan YF, Tao XM, Yick KL, Crystallization and prevention of supercooling of microencapsulated n-alkanes.
[36] C. C. Chang, Y. L. Tsai, J. J. Chiu, H. Chen, Preparation of phase change materials microcapsules by using PMMA network‐silica hybrid shell via sol‐gel process, Journal of Applied Polymer Science, 112 (2009) 1850
[37] J. Brenner, Perfum. Flavour, 8 ,1983, 40
[38] Li W, Zhang XX, Wang XC, Niu JJ, Preparation and characterization of microencapsulated phase change material with low remnant formaldehyde content, Mater Chem Phys, 106 (2007) 437-442.
[39] 林岩錫，魏麒書，相變材料微膠囊在紡織品上應用，紡織綜合研究期刊，第十四卷，第四期，(2004) 359-364
[40] 葉宗賢，「聚氨基甲酸酯-聚脲微膠囊製備及其控制釋放之研究」，逢甲大學紡織工程研究所碩士論文 (2005)
[41] 黃士芳，「以正十八烷製備相轉移材料微膠囊」，國立中央大學化學工程與材料工程學系碩士論文 (2010)
[42] 張智中，「以溶膠-凝膠法製備有機無機混成相轉移材料微膠囊」，國立中央大學化學工程與材料工程學系碩士論文 (2006)
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