Silicon-induced ene-type reaction in the thermal conversion of enolates to beta-silyl enones with molecular dioxygen

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題名:	Silicon-induced ene-type reaction in the thermal conversion of enolates to beta-silyl enones with molecular dioxygen
作者:	Hwu,Jih Ru;Chen,Chien Hsien;Hsu,Chuan-I;Das,Asish R.;Li,Yen Cheng;Lin,Lung Ching
貢獻者:	化學研究所
關鍵詞:	NORRISH TYPE-I;DIRECTED DECARBONYLATION;ORGANOSILICON COMPOUNDS;ELECTROCHEMICAL METHOD;UNSATURATED KETONES;CARBONYL-COMPOUNDS;ELECTRON-TRANSFER;ORGANIC-SYNTHESIS;SINGLET OXYGEN;OXIDATION
日期:	2008
上傳時間:	2010-07-07 11:55:31 (UTC+8)
出版者:	中央大學
摘要:	Reaction of alkyl, acetoxy, and silyl enol ethers of 3-(organosilyl)cyclohexanone with molecular dioxygen in toluene at 110 degrees C produced the corresponding conjugated enones in yields up to 88% yield. The reaction of the same type failed on replaceme
關聯:	ORGANIC LETTERS
顯示於類別:	[化學研究所] 期刊論文

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