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| 題名: | Synthesis, characterization, and properties of the first indium borogermanate incorporating an organic amine ligand: InBGe2O 6(OH)2(CH3CH(NH2)CH 2NH2)�2H2O |
| 作者: | 李光華;Wang, Chih-Min;Chiu, Cheng-Wei;Lin, Hsiu-Mei;Lii, Kwang-Hwa;Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan, ROC |
| 貢獻者: | 理學院化學學系 |
| 關鍵詞: | ABSORPTION SPECTROSCOPY;AMINES;ATOMS;BORON;CRYSTALS;EMISSION SPECTRA;EMISSION SPECTROSCOPY;GERMANIUM;INDIUM;INFRARED SPECTRA;INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;LIGANDS;MOLECULES;SYNTHESIS;THERMAL GRAVIMETRIC ANALYSIS |
| 日期: | 2013-11-06 |
| 上傳時間: | 2026-04-21 14:15:44 (UTC+8) |
| 出版者: | Academic Press Inc.;United States |
| 摘要: | 摘要： A new indium borogermanate incorporating an organic amine ligand, InBGe{sub 2}O{sub 6}(OH){sub 2}(CH{sub 3}CH(NH{sub 2})CH{sub 2}NH{sub 2})·2H{sub 2}O, was synthesized under solvothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy. This compound is a new example of the combination of metal, boron, and germanium atoms into one structure in the presence of organic amine molecules. Its 2D sheets with one 3-, one 4-, and two types of 6-membered rings consist of In{sub 2}O{sub 6}N{sub 4} octahedral dimers, Ge{sub 2}O{sub 6}(OH) double tetrahedra, and BO{sub 3}(OH) groups that are interconnected by water molecules to form a 3D supramolecular framework. Interestingly, the emission spectrum for this compound displays a strong broad band centered at 455 nm. - Graphical abstract: The first example of indium borogermanate incorporating an organic amine ligand was synthesized under solvothermal conditions. Infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy have also been studied.
出版者： United States
出版日期： 2013-12-15
出處： Journal of solid state chemistry, 2013-12, Vol.208
識別號： ISSN: 0022-4596
識別號： EISSN: 1095-726X
識別號： DOI: 10.1016/J.JSSC.2013.09.021 |
| 顯示於類別: | [化學學系] 期刊論文
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