摘要： We demonstrate that cyclooctatetraene (COT) can be stabilised in different conformations when adsorbed on different noble-metal surfaces due to varying molecule-substrate interactions. While at first glance the behaviour seems to be in accordance with Hückel's rule, a theoretical analysis reveals no significant charge transfer. The driving mechanism for the conformational change is hybridisation at the organic-metal interface and does not necessitate any charge transfer. 其他題名： Chem Commun (Camb) 出版者： England 出版日期： 2013-07-07 出處： Chemical communications (Cambridge, England), 2013-07, Vol.49 (53), p.5993-5995 資源來源： Royal Society of Chemistry 識別號： ISSN: 1359-7345 識別號： ISSN: 1364-548X 識別號： EISSN: 1364-548X 識別號： DOI: 10.1039/c3cc42574f 識別號： PMID: 23719739
