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| 題名: | In-canopy gas-phase chemistry during CABINEX 2009: Sensitivity of a 1-D canopy model to vertical mixing and isoprene chemistry |
| 作者: | 谷邁世;Bryan, A. M.;Bertman, S. B.;Carroll, M. A.;Dusanter, S.;Edwards, G. D.;Forkel, R.;Griffith, S.;Guenther, A. B.;Hansen, R. F.;Helmig, D.;Jobson, B. T.;Keutsch, F. N.;Lefer, B. L.;Pressley, S. N.;Shepson, P. B.;Stevens, P. S.;Steiner, A. L. |
| 貢獻者: | 地球科學學院大氣科學學系 |
| 關鍵詞: | Atmospheric chemistry;Canopies;Deciduous forests;Environmental Sciences;Isoprene;Mixed forests;Monoterpenes;Ocean, Atmosphere;Organic compounds;Oxidation;Sciences of the Universe;VOCs;Volatile organic compounds |
| 日期: | 2012-11-19 |
| 上傳時間: | 2026-04-21 13:37:21 (UTC+8) |
| 出版者: | European Geosciences Union;Katlenburg-Lindau: Copernicus GmbH |
| 摘要: | 摘要： Abstract. Vegetation emits large quantities of biogenic volatile organic compounds (BVOC). At remote sites, these compounds are the dominant precursors to ozone and secondary organic aerosol (SOA) production, yet current field studies show that atmospheric models have difficulty in capturing the observed HOx cycle and concentrations of BVOC oxidation products. In this manuscript, we simulate BVOC chemistry within a forest canopy using a one-dimensional canopy-chemistry model (Canopy Atmospheric CHemistry Emission model; CACHE) for a mixed deciduous forest in northern Michigan during the CABINEX 2009 campaign. We find that the base-case model, using fully-parameterized mixing and the simplified biogenic chemistry of the Regional Atmospheric Chemistry Model (RACM), underestimates daytime in-canopy vertical mixing by 50–70% and by an order of magnitude at night, leading to discrepancies in the diurnal evolution of HOx, BVOC, and BVOC oxidation products. Implementing observed micrometeorological data from above and within the canopy substantially improves the diurnal cycle of modeled BVOC, particularly at the end of the day, and also improves the observation-model agreement for some BVOC oxidation products and OH reactivity. We compare the RACM mechanism to a version that includes the Mainz isoprene mechanism (RACM-MIM) to test the model sensitivity to enhanced isoprene degradation. RACM-MIM simulates higher concentrations of both primary BVOC (isoprene and monoterpenes) and oxidation products (HCHO, MACR+MVK) compared with RACM simulations. Additionally, the revised mechanism alters the OH concentrations and increases HO2. These changes generally improve agreement with HOx observations yet overestimate BVOC oxidation products, indicating that this isoprene mechanism does not improve the representation of local chemistry at the site. Overall, the revised mechanism yields smaller changes in BVOC and BVOC oxidation product concentrations and gradients than improving the parameterization of vertical mixing with observations, suggesting that uncertainties in vertical mixing parameterizations are an important component in understanding observed BVOC chemistry.
出版者： Katlenburg-Lindau: Copernicus GmbH
出版日期： 2012-09-28
出處： Atmospheric Chemistry and Physics, 2012-09, Vol.12 (18), p.8829-8849
資源來源： Agricultural & Environmental Science Collection
版權： COPYRIGHT 2012 Copernicus GmbH
版權： Copyright Copernicus GmbH 2012
版權： licence_http://creativecommons.org/publicdomain/zero
識別號： ISSN: 1680-7324
識別號： ISSN: 1680-7316
識別號： EISSN: 1680-7324
識別號： DOI: 10.5194/acp-12-8829-2012 |
| 顯示於類別: | [大氣科學學系] 期刊論文
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